Hi Graham,
The title of your post and the question you ask in it raise slightly different aspects. Lyn has answered the latter but as to whether the RT will stop your PSA rising really depends on how well the radiographer has been guided to deliver your RT which will be at and close to the Prostate bed. If it is has spread beyond where the RT is directed, the chance of it being successful is less. Unfortunately, it's a question of following post RT PSA tests. Microscopic cancer cells are unlikely to show on a scan so no help there. Very much hope the RT does the job for you.
Do let us know how it works out.